
Figure1: Spectral Sensitivity curves for VRP-M
(left) and PFG-01 (right).

Figure 2: Characteristic Curves for VRP-M
(left) and PFG-01 (right).

Figure 3: Grain Size Distribution Curve for VRP-M and PFG-01.

Figure 4: Diffraction Efficiency Curves for
VRP-M and PFG-01. |
|
Characteristic
curves of fine-grain red (PFG-01) and green (VRP-M) emulsions,
showing spectral sensitivity versus wavelength, are shown in Fig.1.
The VRP-M optical sensitivity (to CW radiation) is seen to peak
at approximately 75 mJ/cm2 and that of the PFG-01 (to
CW radiation) at approximately 80 mJ/cm2.
Fig.2
shows the optical density after exposure by CW radiation and
after development versus energy. Grain size characteristics for
the VRP-M and PFG-01 emulsions are shown in Fig.3.The
diffraction efficiency versus exposure for reflection holograms
recorded on PFG-01 (using a CW laser) and on VRP-M (using a
pulsed laser) is presented in Fig.4. The
maximum diffraction efficiency is seen to be >45% for both
emulsions. Material lifetime is more than two years.
The VRP-M and PFG-01 emulsions may be used equally well with
pulsed lasers and with CW radiation. In the pulsed laser
radiation case the emulsion should be post-sensitized with the
technique of latensification. The latensification technique is
described below.
Table1 shows a summary of recommended
processing schemes for use with VRP-M when exposed by pulsed
Neodymium lasers (526.5nm, 532nm) and for use with VRP-M and
PFG-01 when exposed by CW Argon or by HeNe lasers. In the case
of exposure by CW radiation latensification is usually not
necessary.
White-light holograms made on VRP-M have a natural green
reconstruction colour that can be easily changed by the
technique of colour -shifting using D-Sorbitol (described
below). White-light holograms made on PFG-01 have a natural
yellow/orange reconstruction colour when using a HeNe laser and
the recommended chemistry.
All chemicals necessary for the preparation of the recommended
solutions can be obtained from the following companies -
(i) Photographer s Formulary Inc. (www.photoformulary.com),
(ii) Sigma-Aldrich www.sigma-aldrich.com),
For pulsed work one may also use the standard D-19 Kodak
developer if 6-8g of Methyl Phenidone is added into the final
solution.
The temperature of all solutions described herein is 20 0C
|
| VRP-M
&PFG-01 |
Mastering
and Copying with Pulsed
Radiation |
Mastering
and Copying with CW Radiation. |
| Exposure: |
|
|
|
MASTERING
|
20-40
mJ/cm2 |
60-80
mJ/cm2 |
| COPYING |
30-60
mJ/cm2 |
70-90
mJ/cm2 |
| Latensification |
Yes |
If
needed |
| Development |
SM-6,
2min |
CW-C2,
2min |
| Wash |
Water,
1-2min |
Water,
1-2min |
| Bleach |
PBU-Amidol
until clear (~2-3 min) |
PBU-Amidol
until clear (~2-3 min) |
| Wash |
Water
5 mins |
Water
5 mins |
| Final Wash |
Water
with wetting agent (Agepon) 1min |
Water
with wetting agent (Agepon) 1min |
| Drying |
Slow
Air |
Slow
Air |
Table 2:
Recommended Processing for VRP-M and PFG-01.
|
|
SM-6
Developer
|
| Sodium Hydroxide |
12.0g |
| Methyl Phenidone |
6.0g |
| Ascorbic Acid |
18g |
| Sodium Phosphate
(dibasic) |
28.4g |
| if 12H2O |
71.6g |
| Water |
to
1.0L |
|
CW-C2
Developer
1 part A + 1 part B
|
| Part
A |
| Catechol |
20.0g |
| Ascorbic Acid |
10.0g |
| Sodium Sulphite
(anhydrous) |
10.0g |
| Urea |
100.0g |
| Water |
to
1.0L |
| Part
B |
| Sodium
Carbonate |
60.0g |
| Water |
to
1.0L |
| PBU-Amidol
Bleach |
| Potassium
Persulphate |
10.0g |
| Citric Acid |
50.0g |
| Cupric Bromide |
1.0g |
| Potassium Bromide |
20.0g |
| Amidol |
1.0g |
| Water |
to 1.0L |
| Potassium
Iodide Bath |
| Potassium Iodide |
18.0g |
| Water |
to 1.0L |
Table 2: Developers, bleach
and colour chance bath

Figure 5: Hologram Colour versus
D-Sorbitol Solution Concentration for
exposure @ 526 nm
|
|
Latensification
PFG-01
and VRP-M emulsions have peak sensitivities to exposures
in the millisecond regime. In order to obtain optimal
sensitivity to exposures different from this regime the
technique of latensification must be used.
Latensification is usually done directly after the
holographic exposure. Before applying the process a
latensification time appropriate for your system must be
worked out. This procedure is as follows: Place a 25W
white lamp at a distance of 1m from a test holoplate or
film such that its light uniformly illuminates the
emulsion. You will need to try several exposure times.
First of all you will need to develop the unexposed
emulsion under normal safelight conditions. The plate
will darken a little. This is called the fog
level. After development wash this control plate, dry
and keep it handy. Now a series of exposures with small
test plates must be made. Start at about 2 secs and go
up to around 10 secs. After each exposure develop your
plate and match the darkening of this plate to your
control plate. If it is the same, more exposure is
needed so go back and repeat the process. Stop when a
result that is just marginally darker than the fog level
is obtained. This is then the correct latensification
exposure for your geometry.
Now that the proper latensification time has been
discovered, after every proper holoplate exposure you
must take your plate and illuminate it exactly as
described above for the time that you have worked out.
Then all processing is as normal.
Latensification stabilizes and enhances the latent image
formed by the holographic exposure. If required,
chemical processing may be done with significant delay
after latensification (~8 hours).
Colour
control
For
the VRP-M emulsion we recomend two colour shifting
techniques. One produces a fixed colour-shift towards
the red of approximately 50 nm. The other produces an
adjustable colour shift.
The fixed colour shifting is accomplished by soaking the
final hologram for 1 minute in a bath of Potassium
Iodide solution. Adjustable colour shifting is
accomplished by soaking the hologram for 1 minute in an
aqueous solution of D-Sorbitol (sugar substitute -
C6H14O6) with added wetting agent. The colour of the
final hologram depends on the solution concentration (Fig.5).
After soaking, the film must be taken out and put onto a
flat surface. Water drops must be removed using a
rubber wiper such as a windscreen wiper. Here one must
be delicate - if too much force is employed you may
obtain a somewhat different colour than that predicted
by Fig. 5. If, after drying of the
hologram, the replay colour achieved is not
satisfactory, the film or plate may be washed in warm
water and then soaked anew in another D-Sorbitol
solution of different concentration.
|
| |
|
|
|
TITLE
|
CHEMICAL
|
FORMULA
|
Sigma
Aldrich code
|
Fluka
code
|
|
SM-6
|
Sodium Hydroxide
|
NaOH
|
S 0899
|
71690
|
| |
Phenidone
|
C6H5-C3H5N2O
|
P 3441
|
79070
|
| |
Ascorbic Acid
|
CH2OHCHOH(CHCOH:COHCOO)
|
A 7506
|
95212
|
| |
Sodium Phosphate
(dibasic)
|
Na2HPO4
|
S 0876
|
71642
|
|
CW-C2
|
Catechol
|
C6H4-1,2-(OH)2
|
C 9510
|
15890
|
| |
Ascorbic Acid
|
CH2OHCHOH(CHCOH:COHCOO)
|
A 7506
|
95212
|
| |
Sodium Sulphite (anhy.)
|
Na2SO3
|
S 8018
|
71990
|
| |
Urea
|
NH2CONH2
|
U 1250
|
51460
|
| |
Sodium Carbonate
|
Na2CO3
|
S 7795
|
71351
|
|
PBU-Amidol
|
Potassium
Persulphate
|
K2S2O8
|
P 9392
|
60490
|
| |
Citric Acid
|
HOC(COOH)(CH2COOH)2
|
C 0759
|
27488
|
| |
Cupric Bromide
|
CuBr2
|
-
|
61185
|
| |
Potassium Bromide
|
KBr
|
P 9881
|
60095
|
| |
Amidol
|
(NH2)2C6H3OH" 2HCl
|
23,010-3
|
33230
|
|
Bath
|
Potassium Iodide
|
KI
|
P 8256
|
60400
|
|
Hardener
|
Formalin 37%
|
HCHO
|
F 1635
|
47608
|
|
Table
3: Chemical Formulas and suppliers codes.
|
|
|